Tuesday, December 24, 2019

Cultural Appropriation And Its Effects - 1013 Words

Most things in life are not guaranteed. However, a few things are like taxes and cafeteria food being of low quality. Students at Oberlin are complaining about the school’s cafeteria food is racist and â€Å"cultural appropriation†. Cultural appropriation is the act of taking another cultural group’s culture. In this case, it is from poorly made Asian foods like sushi and General Tso’s chicken. They claim that because these foods are poorly made, it is an insult to them and their culture. Most people find this case to be absolutely ridiculous and use it as a way to prove that people can get offended over anything. The whole idea of cultural appropriation is taking culture from a marginalized group. This has recently became a hot issue with the droves of Tumblr and their ilk. The main problem with the people are fighting cultural appropriation is that it makes it so there is no â€Å"right† way to share other people’s cultures around. This is taken to the extreme in this case, it is ridiculous to say that somebody is stealing culture when the food is poorly prepared. From the article, a Japanese student was complaining about the quality of the sushi being prepared at the school and the lack of fresh fish. Well, as a person who enjoys sushi I can easily say that an American school will never be a good place for sushi. Especially a landlocked, tiny liberal arts school in Ohio. Quality sushi is really hard to come by in Ohio, outside of specialized restaurants. That’s not stealingShow MoreRelatedEffects Of Cultural Appropriation On The Fashion Industry1316 Words   |  6 Pag esJulia Raffa English 1110.01 David Winter 23 October 2015 The Effects of Cultural Appropriation in the Fashion Industry The fashion industry is one of the most prevalent and visible forms of influence on today’s society. Billboards, malls, magazines, TV, movies, advertisements, runways, etc. are filled with fashion campaigns usually distributed to make a statement and to influence the consumers. Often times, the fashion industry engages in offensive promotions like romanticizing eating less andRead MoreCultural Appropriation And Its Effect On Society1640 Words   |  7 Pagesregarding race and inequality. One of these major discussions regards cultural appropriation, which is an infamous problem around Halloween. Many individuals are confused by this concept of appropriating culture simply because they cannot distinguish the line between appreciation and appropriation. Thus, these blurred lines lead to offending cultures as well as perpetuating privileges and disadvantages within society. Cultural appropriation, often defined as an â€Å"adoption of elements of one culture by membersRead MoreCultural Appropriation And Its Effect On Society Essay1505 Words   |  7 Pagesto its people. Culture show the struggle the knowledge, the life, and the death of a people. Cultural appropriation is defined as the adaptation or use of elements of one culture by the members of another culture. Seen by some as controversial where minority culture is used by cultural majority (whites), and is seen as stripping it of its importance and intellectual properties.Cultural appropriation, it is something that we as a people should not accept nor should we ignore it.For it has been committedRead MoreCultural Appropriation And Its Effects On Society Essay1679 Words   |  7 Pagessubject of that culture out of context until it is no longer â€Å"special† or â€Å"sacred†? Or is cultural appropriation a term used to reclaim a culture that a group wants to keep for itself? M aybe it’s the assumption all cultures must uphold their own ways of speaking, looking, and living without allowing anyone else to mimic them as to always stand out and hold a place in society. Regardless, cultural appropriation has been a trending topic of conversation and news in the past few years, and thas inhibitedRead MoreCultural Appropriation And Its Effects On Minority Culture948 Words   |  4 Pagesthe amount of cultural appropriation that occurs around them. Westerners are blinded by cultural mockery and cultural appropriation without realizing its offensive effects to minority groups. During the Halloween holiday, in Western culture, people of all ages dress up in a variety of costumes such as horror themed, fairy tale themed, job themed, cultural themed and much more. Harvard University members have argued that a cultural themed costume is a form of cultural appropriation. Also in WesternRead MoreCultural Appropriation And Its Effects On Society1820 Words   |à ‚  8 PagesImagine a world in which cultures where being mocked by dressing like them, making profit from their cultures, and stealing the cultures ideas, this is an example of Cultural Appropriation. â€Å"Cultural appropriation is defined as the adoption or use of elements of one culture by members of a different culture† (Seghal 1). It is not something that has to be imagined as it is the reality that we live in today. Many problems have arisen the past year in ethnicity issues, and it is all due to people notRead MoreCultural Appropriation And Its Effect On Society1495 Words   |  6 PagesIn the simplest of terms, cultural appropriation is loosely defined as an act that occurs when someone of a dominant culture adopts or utilizes certain aspects of a culture that is not their own. However, appropriation goes far beyond that, and can be especially harmful to the marginalized groups that are having their culture appropriated by dominant groups. A deeper look focuses on th e power dynamic that exists within and constitutes appropriation. In other words, when members of a dominant groupRead MoreCultural Appropriation And Its Effects On Society1228 Words   |  5 PagesCultural appropriation is becoming a more and more prevalent problem in society today. It has the negative connotation of taking from another culture. The public doesn’t seem to notice when they are taking another culture, but it is seen as a massive disrespect to the culture because of this. The five authors of the articles all agree that cultural appropriation is the taking from one culture and implementing it into your own; however, the authors opinions differ on what should be done about thisRead MoreCultural Appropriation And Its Effects On Society1965 Words   |  8 Pages Cultural appropriation defines as someone taking or borrowing aspects of another culture that is not their own. Author Lilly Workneh gives a clear definition when stating, â€Å"Appropriation [of a cultu re] occurs when a style leads to racist [assumptions and] generalizations†¦where it originated, but is deemed as high-fashion, cool, or funny when the privileged take it for themselves† (Workneh). Whether it is intentional or not, appropriating a culture involves partaking in the continuation of disempoweringRead MoreThe Negative Implications Of Cultural Appropriation1718 Words   |  7 PagesThe Negative Implications of Cultural Appropriation Samantha Mulcahy INTC 1F90 Jeff Reichheld Seminar 3 Seminar Leader: Jeff Reichheld 13 March 2016 Word Count: 1526 Cultural appropriation is something that is commonly seen around the world in the Grand Narratives of dominant westernized cultures. The cultural appropriation of minority cultures in order to construct the Grand Narratives of dominant cultures has a negative effect on those who are apart of the oppressed minorities. These

Monday, December 16, 2019

Boy in the Striped Pyjamas Free Essays

Bruno’s diary Year 1943, age 9 years old as I was born on the 15th april 1934. Day one of strange happenings: Today I came home from school and maria was in my bedroom going through MY things – Even my secret things. She is just a servant but I tried to be polite when I asked what she thought she was doing. We will write a custom essay sample on Boy in the Striped Pyjamas or any similar topic only for you Order Now Maria never takes all my private things out, she puts things away like she’s supposed too. I asked mother why maria is packing my things but she won’t answer me properly. She just keeps saying we are all going away because of father’s job. She said I’ll have to say goodbye to my friends, my best long life friends. I don’t want to say goodbye to my friends because of father’s job. I know he’s important but why can’t father go by himself and come back later? It’s not fair. I still have lots of plans with my friends that I need to do. I wonder if grandma and grandfather are coming on this holiday too? We can’t really leave them behind†¦though I don’t mind if Gretel stays – shes hopeless. Gretel can look after the house so we can come back to it if this new one isn’t as good. I wonder if the other house has a big bannister like this one that I can slide down? I hope so because it’s my favourite thing to do. Day two of strange happenings: We are at the new house and it’s horrible! It only has three floors, not five like the other one and there are no other children around to play with. I don’t like this place but mother won’t take me back home, she says this is where we live now but I don’t want to live here. Gretel doesn’t like it either, or maria, so it definitely is a horrible place to live. I’ll just have to tell father what a mistake he’s made and then we can all go back home to berlin. Even the people here are scary and boring, like that man that came out of fathers room today. I don’t think I like him†¦he’s too serious. Maria says to steer clear of him anyway. Day three of the horrible place: I scared Gretel today when I showed her the weird children outside my window. She is three years older than me and quite scary, so scaring her isn’t an easy thing to do. I don’t know why she has come with us anyway, all she does is cause trouble. That’s what mother and father say anyway. At least her friends can’t come round anymore. She has horrible friends that call me six when I’m actually nine! She still has her dolls though. I bet they spy on me when I’m in her room, so I don’t go in there much. Gretel said father said we are going to stay here for the foreseeable future, whatever that means. Gretel thinks it’s about 3 weeks, so at least it isn’t a month I suppose. She doesn’t like this place either though so maybe we will move back sooner. Day four of the horrible place: The people outside my window are still there. Gretel thinks that we are in the countryside and that they must be farmers. I don’t think they are farmers though because there are no animals and the ground is all brown and dirty. It doesn’t look like a nice place anyway, there are soldiers shouting at people and for some reason everyone is wearing pyjamas. I wish Gretel knew who they were and would tell me. She’s the brightest girl in her class apparently. I found them though, so they are my people, not hers. I am a high and mighty king in my bedroom and they are my minions that Gretel can’t have. I shall have to ask father what they are doing there and why they don’t have baths. I’ll know more than Gretel then, even though she’s older. Day five: Father came to the house today. We had to leave earlier than father on the train. There were a lot of other people coming this way on the train too†¦but they were all on one big train squashed together. I don’t know why they didn’t just come on the same train as us because we had lots of empty seats they could have used. I was very brave today and asked father when we were going home because it’s horrible here. I thought father would get very angry because I’m not supposed to go into his office or waste his time saying hello or asking silly questions. Father said we have to do things we don’t like though because other people know what’s best for us. He said we have to accept the situation we find ourselves in and then everything will become easier†¦or something like that. I still don’t like it here though and it will never be home. I don’t know why father can’t see that he’s made a mistake. I even told him to apologise to the fury and then we can go back to berlin. Father is a very respectable man but I still think he is wrong. Why doesn’t he just listen to us instead of his job? Extract from chapter 12, pages 128 – 129 †¦we had to move to a different part of Cracow, where the soldiers built a big wall and my mother and father and my brother and I all had to live in one room†¦Ã¢â‚¬ËœThere was one small window in it but I didn’t like to look out of it because then I would see the wall and I hated the wall because our real home was on the other side of it. And this part of town was the bad part because it was always noisy and it was impossible to sleep†¦Ã¢â‚¬ËœThen one day the soldiers all came with huge trucks†¦ And everyone was told to leave the houses. Lots of people didn’t want to and they hid wherever they could find a place but in the end I think they caught everyone. And the trucks took us to a train and the train†¦ The train was horrible†¦ There were too many of us in the carriages for one thing. And there was no air to breathe. And it smelled awful. ’ Shmuel’s exposition provides necessary background information that allows the reader to identify with the character. In this particular extract, the author conjures a lot of imagery to convey emotion and mood, which is implemented through structural and lingual techniques. Ellipses are used repeatedly throughout the extract, creating a pause, which causes the reader to consider and empathise with the characters ordeal. It also contributes to the rhythm of the paragraph, setting a slow and deliberate pace, evoking heightened emotions of fear and apprehension. The simplistic language, combined with alliteration delivers a childlike and innocent approach, which draws sympathy from the reader in relation to the child’s traumatic experience. For example, the ‘soldiers built a big wall’ contrasts against shmuel and his family living in a small room, emphasising how small and vulnerable they are. The use of repetition such as the train is effective in this extract, as it creates a sense of urgency and distress, helping to set a despondent atmosphere. This atmosphere is intensified with short sentences and a hyperbole toward the end of the paragraph (There was no air to breathe) for a dramatic impact. The boy in the striped pyjamas is a fable based on the holocaust. The protagonist of the story, Bruno, comes home from school one day to find his belongings packed and told to say goodbye to his friends due to his dads promotion. Mourning his old home Bruno sets out exploring areas he shouldn’t – his naivety and inquisitive innocence, lead him to the outskirts of a concentration camp, where he befriends a boy just like himself, albeit religious boundaries. It is this friendship between two young boys that leads to a cruel twist of fate. The hamartia of bruno, in this case his innocence, leads to his downfall. It is somewhat ironic, that the innocence and accepting nature of a child is essentially a weakness that leads to a cruel fate, whilst those that deserve misfortune are without tragedy. It also conveys a moral, classifying this book as a fable. In relation, Romeo and Juliet by William Shakespeare share the same themes as the boy in the striped pyjamas. Innocent characters lose their lives unnecessarily because of events that are out of their control, caused by prejudice and discrimination. Another similar feature between the two novels is that Shakespeare uses dynasties/houses to create differences and segregation between parties. In correspondence, the author of the boy in the striped pyjamas, uses clothes to create differences and symbolise their status in society. For example, the striped pyjamas indicates inferiority, weakness and suffering of the jews, whilst the uniforms of the soldiers uphold authority, cruelty and dominance. As opposed to Shakespeare, what makes this book so despairing and emotive is the reality of it. It is not a romantic, fictional play based on lust and fate – it is representative of real events where horrific tragedy’s took thousands of innocent lives for reasons due to nothing but social status, discrimination and prejudice. It can be argued, that such events would not have occurred in reality; firstly, historical records show that more than 6000 soldiers were present in the aushwitz camp, making it unlikely that a child could escape their notice to sit at the edge of a camp and talk to an outsider. Secondly, most women and children were gassed upon their arrival, leaving the men to work. Another point raised, is that most credible 9 year olds have a lot more common sense in reality than is portrayed in this fable. Boyne’s story depends on the overwhelming naivety of his character, who is completely oblivious to the war despite his father working for Hitler. In conclusion, for a short fable aimed at children, I believe it to be a powerfully emotive tale that strikes key points. The innocence and reality of the events that took place in the book make it that much more touching, horrific and powerful. How to cite Boy in the Striped Pyjamas, Essay examples

Sunday, December 8, 2019

Energy Optimized Building Automation †Free Samples to Students

Question: Discuss about the Energy Optimized Building Automation. Answer: Introduction 15th Music Bar is established in Bondi, which offers live music to the customers for their refreshment. This bar contains friendly environment for the guests and maximum guests are Irish who come here. People get fun with a drink in this friendly environment. Drink with live music is the major attraction of this bar. However, Irish cocktail of this bar is popular, which highlights the Irish tradition and culture. Various types of drinks are available in this bar. Drink with music is a major element of the refreshment (Giebelhausen, M. D., Chan, E., Sirianni, 2016). The aim of this bar is to provide relief the guests from their routine bound life by organization live music and by serving a variety of drinks. This study deals with the business planning, product description, and budget planning in the context of 15 th Music Bar. 15th Star Music Bar provides a charming environment for the customers. The name 15th Music bar highlights the live music program that is the especial attraction of this bar. For this reason, the word "Music" is added to this bar name to give a prior idea to the about this bar to the customers. However, this bar would be situated in Bondi where maximum people are Irish. This bar includes full of energy and a vive is present overall space. Providing right ambiance is the aim of this bar, which will allow the customers to spend some extra hours with a drink in this bar. This bar has chosen Bondi for its location that is a posh financial district. Thus, this bar needs a modern and sleek look. It is crucial for 15th music bar to make a survey of the neighborhood and the local restaurants to get an idea about the customer base as well as their needs in this particular location. This bar will include a big space, which will be comfortable for the customers. However, the bar will contain both entry and exit doors to reduce the crowd. On the other hand, maximum furniture of this bar will be wooden and stylish to attract the concentration of the gussets. However, the majority of the customers are Irish, thus this bar needs to focus on the Irish culture and tradition. For this purpose, this bar will offer Irish music that is the main theme. On the other hand, heart food, drink, and friendly culture will be created. This organization will arrange the surprise gift for the guest based on the occasion. The lighting of the bar will not be too strong. The mild light will be used. The tables will be highlighted in this bar and proper orientation of the lighting will be used to guide the guests around the venue. This bar will use the lighting in a way, which can differentiate the space. The warm and cozy light will be used to give comfort to the guests. However, warm a nd cozy light makes the people more comfortable in comparison to other lights (Johnston, 2016). Different color will be used for lighting purpose to make the people charming. A shiny surface will be created on the table to allow the guests to read the menu properly. Service of the bar Service of a bar offers the table service by developing a friendly environment for the guests (Shein et al., 2016). However, it is important for 15th music bar to understand needs of their guests. The success of a bar based on the service standard of the bar. Proper welcome is required. The steps of the bar service is as follow- The guard needs to open the door at first when the guest comes Give a smile and acknowledge the guests at their first appearance Greet the customers within 20 seconds while they are walking through the passage Lead the guests towards their seats and allow them to identify their preferable sitting place Then greet the guests further within 50 seconds after their sitting down Give the menu in front of the guests and allow them to place their order Then take the order and serve the drink within 2 minutes after taking the order Check back the guests if the dropped the order for food or not Then serve the foods within 10 minutes Come to the guests and ask them for any requirement from them After serving the food it is important for the staffs to check the table and the arrangement like water is clean, drink is full or not etc Ask the guests for further assistance Work collaboratively in a team and help the team members Prepare the bill and place it to the customers Give farewell to the customers after completing the payment related work Clear the table as soon as possible after the guests leaving Arrange the table properly to welcome the new guests However, there is very little chance of returning the gusts in a bar who came there for the first time (Lee, Song Lee, 2016). Hence, for this reason, 15th music star needs to identify the exact demand of the guests. In order to retain the customer and to increase the customer loyalty, it is crucial for this bar to understand the tradition, preference, and cultures of the local customers that is the people of Bondi. This will be helpful for this bar to make an intact service for the customers. However, effective communication is required with the guests while giving them service in a bar. Polite behavior and friendly interaction are required for the guest while providing a service within a bar. For 15th music star, they need to create a comfort zone for the guests as comfort level is prior for the guests to enhance the service. On the other hand, it is important for the staffs of such bar to solve any query or any issues regarding the service. Therefore, quick response is required fr om the staffs while serving drinks or foods in this bar. Uniforms of the staffs in 15th music star Staffs should be presentable at any hotel, restaurant, and bar (Nykiel, 2016). However, the bar staffs of 15th music star need to make them smart and presentable in front the guests. However, the uniform of the staffs plays an important role to make the staffs smart. A proper dress up is required for the staffs to attract the guests towards this bar. This organization will decide white skirt and scholars for the female staffs and white shirt with a black coat for the male staffs. Red tie will be mandatory for male and female. However, an enclosed black shoe with a sock is crucial for both male and female. The staffs have to use the logo with the name of the organization in their dress in order to introduce the organization to the customers who will come to the bar. On the other hand, the logo in the dress of the employees also highlights the brand and the culture of the organization. Uniform allows the staffs to look good and feel confident in their working environment (Ataie-Ashtian i, 2016). In the context of 15th music star proper uniform of the staffs, maintain the equality in the workplace. However, the uniform of the staffs will enable this organization to lead the customers to identify the brand and to know who they are. Proper dressing of the staffs will help the guests to identify the staffs. Hence, the uniform of the staffs that is decided by 15th music star will be helpful for them to create brand awareness. Work Place Health and Safety or WHS stated some policies to reduce risk from the workplace. According to Work Health and Safety Act 2011 it is crucial for all the business organization to maintain the health and safety in the workplace (Ikemefuna Enoch, 2016). In the context of 15th music star, it is crucial to provide proper instruction and training to the staffs. Therefore, it is important to develop a healthy culture in the bar to reduce the work-related risk. Implementation of the safety policies will be required for this bar. Therefore, proper arrangement of the first aid, emergency plan and use of protective equipment are required to establish the workplace safety. On the other hand, maintenance of the hygienic factor will be essential for 15th music star as it is a bar and provides food and drink to the customers. The food menu includes starter to dessert based on the Irish tradition. However, many people come to visit the bar and just take a drink. Thus, the starter is a prime part of this bar. On the other hand, according to the alcohol regulation in NSW this bar should provide drink and food at low price, which can be affordable for all classes of customers. The food menu is as follow- Type of food Name Ingredients Price Starters Irish smoked potato pan cakes Potato, butter milk, baking soda, black pepper, butter and sour cream $6 Salmon chowder Salmon fish, bread, butter $8 Irish shrimp crepes Lobster crepes, shrimp $7 Main courses Mushroom chicken Wild mushroom, chicken, mushroom sauce, smash potato, spring onion, and root vegetables $12 Braised lamb Boneless lamb meat, red wine, smashed potato, spring onion, and root vegetables $15 Irish bacon cabbage Boiled bacon, cabbage, spring onion, smashed potato, butter and parsley sauce $13 Salmon pie Salmon fish, green vegetables, spring onion, cabbage, and butter $10 Desserts Cream banoffee pie Sliced banana, toffee, whipped cream $6 Apple pie Apple slice, white cream $7 Table 1: Food Menu (Source: Author) The above food menu will be introduced during the launching of 15th Music bar. This organization has followed the Irish tradition to develop the menu. Drink menu The drink list will include a variety of drink, which may give pleasure the Irish customers as well as the foreign customers. The drink will be prepared to maintain the hygienic factors as health and safety of the customers are necessary for 15th Music bar. The drink list is as follow- Name of the drink Type Price Fanta melon soda Soft drink (Mint and soda) $6 Ginger orange ale Soft drink (Ginger extract, orange) $8 Apple soda Soft drink (Apple and soda) $10 Red cola Soft drink $5 White Russian Hard drink (vodka, milk, and kahlua) $12 Rum and Coke Hard drink (Cola, gold rum, soda) $20 Cosmopolitan Hard drink (Vodka, cranberry juice, lime juice) $15 Vodka and Orange Hard drink (vodka, orange, soda) $18 Vodka and cranberry Hard drink (Vodka, cranberry, soda) $17 Table 2: Drink Menu (Source: Author) The above table includes a variety of drinks in the context of 15th music bar. Both hard and soft drinks are included in this menu and many drinks are prepared based on the Irish tradition. The price of the drink is not too high. As a result, people, from all classes will afford the drinks in this bar. Costing calculation and recipe Vodka 60 ml Cranberry juice 15ml Lime juice 10ml Flavour 1gm Cinnamon Syrup 15 ml Thyme 4 sprigs Method Ingredients Size of the bottle (ML) Price of the bottle $/ml Amount for cocktail recipe cost Vodka 600 $40.00 $0.66 60 ml $39.6 Cranberry juice 300 $50.55 $0.16 15ml $2.4 Lime juice 300 $45.55 $0.15 10ml $1.5 Flavour 5gm $3.00 $0.6 1gm $0.6 Cinnamon Syrup 400 $25 $0.06 15 ml $0.9 Thyme 10 gm $5 $0.5 2 gm $1.00 Table 3: Costing (Source: Author) Maintenance of the sustainability It is important for 15th Music bar to maintain the environmental sustainability while developing a new business. However, for the restaurants and the bar it is crucial to clean the environment (). For reason, 15th Music bar will adopt the CSR activities in their business to reduce the food wastage and keep the environment clean. Conclusion The above piece of work reveals the business plan in the context of 15th Music bar. However, this organization will focus on the Irish culture as it is situated in Bondi where maximum customers are Irish. This organization follows the Irish culture. It has developed a menu regarding the Irish food and drink. However, On the other hand, the menu includes a variety of drinks and foods to satisfy the customers. There proposed service structure is good to retain the customers. Both soft drinks and hard drinks will be available in this bar and the interior design planning is also good. References Ataie-Ashtiani, B. (2016). Declaration of Conflicts of Interest in Networking Era: Raising the Bar.Science and engineering ethics,22(6), 1855-1857. Giebelhausen, M. D., Chan, E., Sirianni, N. J. (2016). Fitting Restaurant Service Style to Brand Image for Greater Customer Satisfaction. Ikemefuna, M., Enoch, M. (2016). Review of Business Plan of Domibite Restaurant, Lokoja, Kogi State, Nigeria.International Business and Management,13(3), 16-21. Johnston, M. (2017).Eclipse Coffee Bar-Business Plan(Doctoral dissertation). Lee, S. A., Song, S. H., Lee, S. M. (2016). Influence of Perceived Service Clues on Experienced Value, Trust, and Loyalty of Franchise Snack Bar.,22(1), 1-8. Nykiel, R. A. (2016).Marketing Your Business-A Guide to Developing a Strategic Marketing Plan. Shein, J. B., Shein, J. B., Bell, M., Bell, M., Whitaker, S. T., Whitaker, S. T. (2017). Jonathan Miller: Custom Energy Bar Entrepreneur Pitches Sharks.Kellogg School of Management Cases, 1-11. Anderson, M., Cessford, M., Dobryshkin, M., Hough, M., Kamimura, S., Meckelborg, K., Weaver, D. (2017). STRATEGIC MARKETING PLAN: NANAIMO CURLING CLUB. Anderson, W., Anderson, W., Busagara, T., Busagara, T., Mahangila, D., Mahangila, D., ... Bahati, V. (2017). The dialogue and advocacy initiatives for reforming the business environment of the tourism and hospitality sector in Tanzania.Tourism Review,72(1), 45-67. McDonald, M., Wilson, H. (2016).Marketing Plans: How to prepare them, how to profit from them. John Wiley Sons. Papargyropoulou, E., Wright, N., Lozano, R., Steinberger, J., Padfield, R., Ujang, Z. (2016). Conceptual framework for the study of food waste generation and prevention in the hospitality sector.Waste management,49, 326-336. Verma, N., Jain, A. (2016, November). Energy optimized building automation with guest comfort in hospitality sector. InComputational Intelligence on Power, Energy and Controls with their Impact on Humanity (CIPECH), 2016 Second International Innovative Applications of(pp. 188-192). IEEE.

Saturday, November 30, 2019

The Problem Of Evil Essays - Philosophy Of Religion, Theodicy

The Problem Of Evil ?If it turns out that there is a God, I don't think that he's evil?the worst that you can say about him is that basically he's an underachiever.? -Woody Allen The Problem of Evil From the viewpoint of theodicy, the problem of evil lies in its origin: Does evil come from God? In spite of God? Using theodicy to define evil is basically an attempt to affirm God's omnipotence and his/her love for humans, with the existence of evil and without contradiction. Depending on your religious background, the weight each of these options carry may vary greatly. A theologian may argue that evil is not a theoretical problem at all, as for it to be a problem, one must question Gods' power, character, and/or existence. To them, even asking the question is a sin. A theologian may also say that evil is a practical truth, as it requires from us the courage to forgive and to heal, or they might also hold the belief that to obtain moral perfection, we must face challenges and overcome them. Other appeals often made by theologians to explain evil might be: a sin is punished with suffering; having free will enables us to make choices, either for good or for evil; and finally that Sa tan is the cause of all evil. From the viewpoint of atheism, it is a question of the existence of God. If God is all-powerful and all-knowing, then evil must not exist apart from God. For it to do so under those criterion would be impossible. This leads one to question the true power of God, and the true good of God. If God is all good, and has the power to stop evil and does not, then God must have a slightly nasty disposition, and therefore is not all good. If God wishes to stop evil and cannot, then God is not all-powerful: he/she is limited. Evil and the Original Sin The doctrine of original sin declares that when Adam ate from the tree of knowledge, he became a moral being by knowing the difference between good and evil, and having the free will to choose between these two dichotomies. This Judeo-Christian story set in the Garden of Eden is said to have great consequences on mankind. Since, according to the bible, Adam is the original father (human being), the sin of Adam is inherited by all beings born to this earthly domain, as we are claimed by the Judeo-Christian culture to be descendants of Adam. When sin entered the world through the sin of Adam, all of mankind became (spiritually) enslaved to sin: we are held in spiritual bondage to sin and the devil. To explain natural evil from the view of the original sin: we (mankind) are dependent on the proper function of our body, and if something goes wrong, we are merely the victim, not the cause of the disturbance to our bodies. We are only human. We cannot control nature, as that is Gods' domain. Therefore, there is some external responsibility with evil To explain moral evil from the view of the original sin: we have free will, and may choose to use that will for good or for evil. Moral evil serves the purpose of challenging our faith and forcing us to face our fears. This is ultimately how one gets to heaven. We are given the freedom to make immoral or moral decisions, and having that choice allows us to choose the road we wish to walk upon. Therefore, there is all internal responsibility with sin. Evil and Soul Building The soul building theodicy carries a strong hope for the future with its ultimate destiny for mankind being a close relationship with God in an eternal life.. Soul building ignores neither the arbitrary nor the excessive evil in our world. This theodicy suggests that God desires personal relationships with men and women; that God desires fellowship with humanity. It does not necessarily allude to God desiring relationships with perfect people; rather a relationship with mature people. According to the soul building theodicy, this maturity is reached by withstanding the difficult (evil?) circumstances put before you. In the soul building theodicy, there is an element of future hope. The reason for

Tuesday, November 26, 2019

The best custom essay writing services

The best custom essay writing services The fact that custom essay writing services are here does not guarantee academic success. There are a few who offer genuine services while others out to frustrate students. And knowing very well how students are quick to agree, they take it as a life time opportunity. Such a custom writing service goes ahead to completely twist the mind of the students. The fact that they want to get rid of the assignment badly, they hire a company that is only out to steal money. But we are here to prevent students from making wrong choices. Being a custom essay writing service that has existed over 10 years, we continue to educate our customers. We do not want to deal with customers who are not sure whether they are in the right place or not. We provide all the necessary information to guide in choosing the best custom essay writing company. To begin with, is information found on our testimonials page. Find interesting and inviting comments from our previous users. Get a chance to interact with them and enquire more on our services. That is how transparent our company and our services are. We give the best in order to receive the best. Another way to know if a service is good is by number of orders placed. If a service is genuine it will definitely attract more customers meaning more orders. Check out our custom writing services reviews and see company ratings. Due to their affordable prices, high quality and good customer response our ratings are amazing. We urge all students to read our reviews before placing their order. They should be able to anticipate the kind of experience we will offer as they place their order. Do not be cheated by anyone who needs to be hired. As much as online essay writing is offered, give it a thought. Do not go for a service that will stress you the entire semester. Its better to take time looking for a reliable and trust worthy service and get your assignment in a week. Go through each custom writing website one by one until you are sure of your choice. If in a complete fix, our professional writers will give additional assistance. Find the best custom essay writing company with our specialized service that has many reviews and testimonials from real customers.

Friday, November 22, 2019

The Battle of the Alamo 1836 - Texas Revolution

The Battle of the Alamo 1836 - Texas Revolution Battle of the Alamo -  Conflict Dates: The siege of the Alamo took place from February 23 to March 6, 1836, during the Texas Revolution (1835-1836). Armies Commanders: Texans Colonel William Travis Jim BowieDavy Crockett180-250 men21 guns Mexicans General Antonio Là ³pez de Santa Anna 6,000 men20 guns Background: In the wake of the Battle of Gonzales which opened the Texas Revolution, a Texan force under Stephen F. Austin encircled the Mexican garrison in the town of San Antonio de Bà ©xar. On December 11, 1835, after an eight-week siege, Austins men were able to compel General Martà ­n Perfecto de Cos to surrender. Occupying the town, the defenders were paroled with the requirement that they forfeit the majority of their supplies and weapons as well as not fight against the Constitution of 1824. The fall of Cos command eliminated the last major Mexican force in Texas. Returning to friendly territory, Cos provided his superior, General Antonio Là ³pez de Santa Anna, with information about the uprising in Texas. Santa Anna Prepares: Seeking to take a hard line with the rebelling Texans and angered by perceived American interference in Texas, Santa Anna ordered a resolution passed stating that any foreigners found fighting in the province would be treated as pirates.   As such, they would be immediately executed. While these intentions were communicated to US President Andrew Jackson, it is unlikely that many of the American volunteers in Texas were aware of the Mexican intention to forego taking prisoners. Establishing his headquarters at San Luis Potosà ­, Santa Anna began assembling an army of 6,000 with the goal of marching north and putting down the revolt in Texas. In early 1836, after adding 20 guns to his command, he began marching north through Saltillo and Coahuila. Fortifying the Alamo: To the north in San Antonio, Texan forces were occupying the Misià ³n San Antonio de Valero, also known as the Alamo. Possessing a large enclosed courtyard, the Alamo had first been occupied by Cos men during siege of the town the previous fall. Under the command of Colonel James Neill, the future of the Alamo soon proved a matter of debate for the Texan leadership. Far from the majority of the provinces settlements, San Antonio was short on both supplies and men.   As such, General Sam Houston advised that the Alamo be demolished and directed Colonel Jim Bowie to take a force of volunteers to accomplish this task. Arriving on January 19, Bowie found that work to improve the missions defenses had been successful and he was persuaded by Neill that the post could be held as well as that it was an important barrier between Mexico and the Texas settlements. During this time Major Green B. Jameson had constructed platforms along the missions walls to allow the emplacement of captured Mexican artillery and to provide firing positions for infantry. Though useful, these platforms left the upper bodies of the defenders exposed. Initially manned by about 100 volunteers, the missions garrison grew as January passed. The Alamo was again reinforced on February 3, with the arrival of 29 men under Lieutenant Colonel William Travis. A few days later, Neill, departed to deal with an illness in his family and left Travis in charge. Travis ascent to command did not sit well with Jim Bowie. A renowned frontiersman, Bowie argued with Travis over who should lead until it was agreed that the former would command the volunteers and the latter the regulars. Another notable frontiersman arrived on February 8, when Davy Crockett rode into the Alamo with 12 men. The Mexicans Arrive: As preparations moved forward, the defenders, relying on faulty intelligence, came to believe that the Mexicans would not arrive until mid-March. To the surprise of the garrison, Santa Annas army arrived outside of San Antonio on February 23. Having marched through driving snow and foul weather, Santa Anna reached the town a month sooner than the Texans anticipated. Surrounding the mission, Santa Anna sent a courier requesting the Alamos surrender. To this Travis responded by firing one of the missions cannon. Seeing that the Texans planned to resist, Santa Anna laid siege to the mission. The next day, Bowie fell ill and full command passed to Travis. Badly outnumbered, Travis sent out riders asking for reinforcements. Under Siege: Traviss calls went largely unanswered as the Texans lacked the strength to fight Santa Annas larger army. As the days passed the Mexicans slowly worked their lines closer to the Alamo, with their artillery reducing the missions walls. At 1:00 AM, on March 1, 32 men from Gonzales were able to ride through the Mexican lines to join the defenders. With the situation grim, legend states that Travis drew a line in the sand and asked all those willing to stay and fight to step over it. All except one did. The Final Assault: At dawn on March 6, Santa Annas men launched their final attack on the Alamo. Flying a red flag and playing the El Degà ¼ello bugle call, Santa Anna signaled that no quarter would be given to the defenders. Sending 1,400-1,600 men forward in four columns they overwhelmed the Alamos tiny garrison. One column, led by General Cos, broke through the missions north wall and poured into the Alamo. It is believed that Travis was killed resisting this breach. As the Mexicans entered the Alamo, brutal hand-to-hand fighting ensued until almost the entire garrison had been killed. Records indicate that seven may have survived the fighting, but were summarily executed by Santa Anna. Battle of the Alamo -  Aftermath: The Battle of the Alamo cost the Texans the entire 180-250-man garrison. Mexican casualties are disputed but were approximately 600 killed and wounded. While Travis and Bowie were killed in the fighting, Crocketts death is a subject of controversy. While some sources state that he was killed during the battle, others indicate that he was one of the seven survivors executed on Santa Annas orders. Following his victory at the Alamo, Santa Anna moved quickly to destroy Houstons small Texas Army. Outnumbered, Houston began retreating towards the US border. Moving with a flying column of 1,400 men, Santa Anna encountered the Texans at San Jacinto on April 21, 1836. Charging the Mexican camp, and yelling Remember the Alamo, Houstons men routed Santa Annas troops. The next day, Santa Anna was captured effectively securing Texan independence. Selected Sources The AlamoBattle of the AlamoTexas State Library: Battle of the Alamo

Thursday, November 21, 2019

The Fall of the House of Usher Essay Example | Topics and Well Written Essays - 750 words

The Fall of the House of Usher - Essay Example To be specific, psychological thrillers combine gothic elements and human psychology and entertain human minds. Besides, Poe leads the readers towards the secrets hidden inside the layers of human mind. So, Poe’s literary craftsmanship is beyond the scope of traditional mode of storytelling. One can see that Poe’s works help the readers to analyze the problems faced by the characters from a different angle of view. Thesis statement: The Fall of the House of Usher by Edgar Allan Poe can be regarded as a psychological thriller because the same exposes the deep relation between horror and insanity. This essay is broadly divided into: horror, insanity, and the relationship between horror and insanity. Horror: One can see that the author consciously links the main theme with the element of horror. To be specific, Roderick Usher’s dwelling place itself is the most important aspect of horror in the short story. The geographical location of the house in a remote area, ad ded with strangeness, forces the readers to feel the element of horror. On the other side, Roderick Usher’s strange behavior and his warm relationship with the narrator creates doubt in the minds of the readers. But the sudden twist in the story, related to the strange incidents at Roderick Usher’s dwelling place, leads the readers towards an illusionary world of horror. Still, the narrator tries to be cordial with Roderick Usher and his sister. But this does not help Roderick Usher to maintain his emotional equilibrium. On the other side, Madeline’s fate as the victim to her brother’s hallucination adds the element of horror to the plot. Kirsten Hinzpeter states that, â€Å"Madeleine’s illness which stuns even the physicians would additionally be a source of terror† (60). At the same time, Poe provides ample importance to unexpected events in the short-story. This unexpectedness, added with gothic setting, accelerates the free flow of the e lement of horror in the work. In short, the author’s interest in abnormal psychology results in the escalation of the element of horror in the work as a whole. Insanity: Insanity is another element in the short-story that leads the readers to suspect the real aim of the main characters. For instance, the narrator’s decision to visit a family infested with insanity is really suspicious. In this stage, the readers may suspect the narrator as an insane individual. Roderick Usher tries to keep himself as a normal person, but fails to do the same. For example, he tries to forget his illness by immersing himself in music and painting. He does not try to seek sympathy from others, but seeks help from his close friend. Still, his real aim by inviting his friend is ambiguous because he is totally abnormal in his behavior. Roderick Usher does not like to socialize with others in his locality. He leads a secluded life within the interiors of his home. This proves that Roderick Us her is aware of the problem of lunacy faced by his sister and him. Dawn B. Sova states that, â€Å"The dilemma faced by the romantic artist is represented by Roderick, who effectively plunges into madness when he leaves the real world behind in his search for the sublime† (69). But his sister is not an active participant in the story line. In the short-story, she is presented as an individual who is dead. One can guess that Roderick Usher killed his sister and is trying to cover his crime. This ambiguity and hallucination related to the element of insanity leads the readers towards the realms of abnormal psychology. So, one can see that the element of insanity adds strangeness to the main theme of the short-story. Relationship: horror and insanity: The author links the elements of horror and insanity in the short-story to create logical balance to the plot. For instance,

Tuesday, November 19, 2019

Personal financial planning Essay Example | Topics and Well Written Essays - 250 words - 1

Personal financial planning - Essay Example Many countries use the Bismarck System that combines insurance with private health care providers. Most Americans pay for and received medical services in a manner that resembles the Bismarck System, although many insurance providers in other countries are not operated for profit and cannot discriminate against persons for pre-existing medical conditions. The Medicare System of healthcare, like the system in Canada, combines private healthcare providers with government payer insurance. While some American healthcare programs combine private providers with a single government payer, these programs are funded through taxes rather than insurance premiums. A few countries have adopted the Beveridge System of healthcare in which the government is both the provider and payer of healthcare. Healthcare for American military veterans utilizes the Beveridge System. Unlike the healthcare systems in other countries, the American healthcare system combines elements of different systems. It has ye t to be determined how long this mixed system will remain viable. Works Cited Kaiser Commission. â€Å"Medicaid and the Uninsured.† 2010.

Saturday, November 16, 2019

The Significance Of The Inspector Essay Example for Free

The Significance Of The Inspector Essay What Is The Significance Of The Inspector Structurally, Thematically, Linguistically And Contextually In Priestleys An Inspector Calls? How Could An Actor/Director Portray His Role Successfully On Stage? John Priestly first wrote An Inspector Calls in 1945, although it was not performed in England until 1 October 1946. The New Theatre in London hosted the performance by the Old Vic Company. The play is the story of an upper class family, living in the comforts of pre-WWI Britain. As they finish their dinner, a mysterious police officer (known only as the Inspector) enters and questions the family about the suicide of a young woman, breaking them down and changing their moral opinions. The focus of the play is this journey that the family under go from ignorance to knowledge, brought on by the Inspectors presence. This essay will explore how big a part of the plot the Inspector is and how he could be portrayed in a production successfully. Arguably one of the most important traits of the Inspector is his use of language. He uses his choice of words to change the atmosphere, the mood of the characters and the pace of the conversation. When the Inspector enters at the beginning of the play, he appears in no rush to question the characters or even explain why he is there. This annoys Birling, as he is curious why this mysterious policeman is visiting: BIRLING: Well, what can I do for you? Some trouble about a warrant? INSPECTOR: No, Mr Birling. BIRLING: (after a pause, with a touch of impatience) Well, what is it then? The Inspector uses the familys fascination to ensure that he is always listened to and is in control. He is the only character in the play at this time that knows the purpose of his visit, and this complete knowledge of the case runs throughout the play, and has different effects on different characters. The Inspector feels that everyone should feel a sense of responsibility for each other. He disapproves of the family members attempts to distance themselves from the girl and displays this when talking to Mrs Birling: She came to you for help, at a time when no women could have needed it more. And you not only refused it yourself but saw to it that others refused it to. The Inspector is trying to evoke sympathy for the girl by not only stating facts but also adding extra, emotive details such as when no women could have needed it more. The Inspector also, through his actions and possibly supernatural ways, creates a presence that makes the other characters listen to him without question. It says that when he enters for the first time that he creates a sense of massiveness and purposefulness. The Inspector even manages to do things that would be judged as completely unacceptable by the Birlings if anyone else were to do it, such as interrupting the head of the household: INSPECTOR: (cutting in smoothly) Just a minute Mr Birling. The Inspectors calm and composure creates a sense of authority about him and uses his presence to allow him to direct the conversation when he feels that it is drifting away from the central message of the play. The character of the Inspector not only changes the direction of conversation when he wants to, but also changes the tempo of it according to the attitude of the person he is interviewing. For example, when he is questioning Sheila, the Inspector only lightly prompts her to tell her story: INSPECTOR: (cutting in) Never mind about that. You can settle that between you afterwards. What happened? Through this short open-ended question, the Inspector provokes Sheila to confess to using her influence to ensure Eva Smith lost her job. With someone more tightly lipped, such as Mrs Birling, the Inspector uses lots of short questions, as she is unwilling to give an account of events: INSPECTOR: She appealed to your organisation for help? MRS B: Yes. INSPECTOR: Not as Eva Smith? MRS B: No. Nor as Daisy Renton. INSPECTOR: As what then? MRS B: First she called herself Mrs Birling By changing the velocity of the exchange, the Inspector not only adapts his questions to the suspect but even possibly shock them into a confession. With Sheila the Inspector is supportive, maybe even sympathetic, towards her as she is clearly the most sensitive to the death. As Sheila is already showing remorse for her actions, the Inspector isnt unnecessarily cruel to her, although he is still concrete on the fact that what Sheila did was wrong. With Mrs Birling however, she appears not to regret her conduct or even feel sorrow for the girls death. The Inspector therefore changes his approach accordingly, asking her short questions and trying to get her to empathise with Eva Smith. When this fails, the Inspector then reveals Evas deserting lover to be Eric. The shock of this revelation completely destroys Mrs Birlings mental barrier between her and Eva.

Thursday, November 14, 2019

Alcohol Policy Done Wrong :: Argumentative persuasive Alcohol Policy Essays

Alcohol Policy Done Wrong When I was elected Interfraternity Council Treasurer in December of 1997 I knew I was in for a long semester, but I never knew what might evolve. I was elected in the wake of alcohol problems across the country. The only alcohol problem I knew of that had happened at the University of Arkansas involved a fraternity on bid day (the day when new freshman receive their invitation to a fraternity house). It involved two students that drank so much alcohol that they had to be rushed to the hospital. Both students were released from the hospital and the fraternity was placed on alcohol probation. I happened to be a newcomer to that fraternity as well and all alcohol probation meant to the fraternity was that they had to be a little more careful about where they drank alcohol in the house. The University of Arkansas has been very lenient in the past about enforcing the alcohol policy. The University’s policy is dated February 22, 1974. The policy states, â€Å"Possession and use of intoxicants in public areas of University facilities (including organized houses) and at official University functions held on campus is prohibited. Persons of legal age as prescribed by state law regarding alcoholic beverages may possess and consume these beverages in the privacy of assigned student rooms. Irresponsible behavior while under the influence of intoxicants is not condoned and may be subject to review and/or action by the appropriate judicial body.† There has been a lot of criticisms to the alcohol policy. First, the fact that it was written in 1974 attracts a plethora of criticisms. I feel that many things have changed since the 70’s and the alcohol policy should also change. Another thing that attracts criticism is the way it has been forced. I hav e seen pictures in the University of Arkansas yearbook from 1970 that show members of fraternities sitting on the roofs of their houses drinking beer out of the can, which is a direct violation of the alcohol policy. I have also heard rumors that in the 80’s kegs were clearly present throughout the fraternity houses. The next thing I would like to mention is the sudden change in enforcement of this alcohol policy. I have been on this campus for three years and I have seen an abrupt change in the way administrators enforce the alcohol policy.

Monday, November 11, 2019

Chapter Review 1-3 Principles of Supply Chain Management

Chapter Review 1-3 Principles of Supply Chain Management, 3ed Wisner, Leong, Tan 2012 Chapter Review 1-3 Chapter One: Introduction To Supply Chain Management A Supply Chain is the steps necessary for a manufacturer to procure materials, build a product, and transport the product to consumers. The consumers buy the products based on a combination of cost, quality, availability, maintainability and reputation factors. They hope these products will live up to their needs and expectations. An example of a supply chain that I was involved in while serving in the Air Force would be when I worked in the Supply Squadron. One of our customers, the jet engine maintenance shop, would need a part to repair and F101 engine for use on a B1B bomber aircraft. They would place the order through us. We would place the order with one of our depots that manage the assets. The depots would then place an order with the manufacturer of the asset. The manufacturer of the asset would be our second-tier supplier. The depots would be our first-tier supplier. The jet engine maintenance shop would be our first-tier customer, and the flight line mechanics would be our second-tier customer that needed the engine to install on the aircraft. The end product consumers would be the recipients of the mission to be accomplished by the aircraft crew. The three definitions of supply chain management in the text are all stated differently but pretty much mean the same thing; planning and managing the processes of procuring assets, converting assets into products, and delivering them to a customer. Of course there is much more detail involved getting from one end of the chain to the other and back again when necessary. There are four foundation elements of supply chain management. The supply elements are all about the purchasing and strategic concepts of supply management. The operations elements consist of several internal operations that oversee the assembling of parts into a finished product that meets all specifications and customer requirements. The logistics elements deal with the storing of the completed product and transporting it to the customer. The integration elements deal with the process integration of all the processes among the focal firm and their partners. Through the use of lean and Six Sigma methodology, improvements in the supply chain processes can be made and costs lowered. As the conditions change around the world, supply chain management will continue to change with it. Questions 1. What is a company that is hired to manage all of a firm’s logistics and supply chain management called? Answer: Fourth-Party Logistics Provider or 4PL (Page 10) 2. What is meant by perfect order fulfillment? Answer: Orders that arrive on time, complete and damage free. (Page 20) 3. What is right-shoring? Answer: The combination of on-shore, near-shore and far-shore operations into a single, flexible, low-cost approach to supply chain management. (Page 23) 4. What are Reverse Logistics Activities? Answer: When customers return products, get warranty repairs or recycle items. . What is the radical rethinking and redesigning of business processes to reduce waste and increase performance? Answer: Business Process Reengineering or BPR. (Page 14) Chapter Two: Purchasing Management The goal of Supply Management in an organization is to ensure a continual flow of raw materials at the lowest cost possible. Another goal is to improve the quality of the finished goods produc ed as well as increase customer satisfaction. By obtaining these goals supply management has proven to be a key strategic business process and not just another supporting function of the business. Done well a company can give itself an edge over other companies that are not meeting these goals. Using smarter purchasing is another way for a company to increase profitability. Cutting costs and boosting sales are not the only way to improve profits. For instance, if a firm reduces its purchase spend on materials through a more effective purchasing strategy they will increase their return on assets. This is also likely to lower raw material inventory and total assets. E-Procurement brought many benefits to companies. It has proven to be a time saver and cost effective. It is more accurate as the information is only entered once instead of twice. Before the users had to enter the information and the buyer had to reenter the information creating another error point in the process. E-procurement is more flexible as it can be used without the restrictions of location or time of day. Status of orders can be looked at without having to check paper trails. There are different reasons why a firm may use a single supplier instead of favoring multiple suppliers. Using a single supplier gives a firm the chance to build a stronger relationship with the supplier. Costs would be lower due to larger purchases keeping the cost per unit down and transportation would be cheaper as the firm can take advantage of full truckloads. Single sourcing would also make sense if the firm’s requirements are too small. It would not be worthwhile to split the order among multiple suppliers. There is a disadvantage with sole sourcing as well. If the purchase was for a proprietary product or process and the supplier holds the patents to them, the firm has no choice but to buy from them. Multiple sourcing is advantageous for many reasons. If the demand is greater than the capacity of a single supplier, having more than one supplier would help to keep up with the demand. It gives firms options in case of interruptions that have affected any given supplier. Competition is created among the suppliers in terms of price and quality. You would have more sources of information about the market conditions, product developments and new technologies. Questions 1. What are the primary goals of purchasing? Answer: To ensure uninterrupted flow of raw materials at the lowest total cost, to improve quality of the finished product and to maximize customer satisfaction. (Page 40) 2. The list of suppliers that a firm uses to acquire materials, services, supplies and equipment is called what? Answer: The supply base or supplier base. (Page 57) 3. What are the six advantages of centralization? Answer: Concentrated volume, avoid duplication, specialization, lower transportation costs, no competition within units and common supply base. (Page 62) 4. What is the difference between direct and indirect offset? Answer: Direct offset usually involves co-production, or a joint venture and exchange of related goods or services; whereas indirect offset involves exchange of goods or services unrelated to the initial purchase. Page 65) 5. What are the three basic types of bid bonds? Answer: Surety bonds, performance bonds and payment bonds. (Page 67) Chapter Three: Creating and Managing Supplier Relationships To have a successful supplier partnership you must understand the key factors for developing them. You must be able to build trust at all levels of management and trust i s very crucial to the success. The partnership should have clear and mutually agreeable shared vision and objectives. When both parties involved have the same goal in mind and have equal decision-making control, the partnership has a higher chance of succeeding. Interpersonal relationships are important as well. It is not just companies talking, it is people talking to people. It is people who make up the companies and are representing them. The companies must be able to manage the change that comes with a new partnership. Communicating information to the people affected by the change. This internal communication is very important so employees can understand why the partnership was formed. Developing performance metrics are a way to evaluate how well suppliers are doing. Information gathered can help improve the entire supply chain. Organizations can identify suppliers that have exceptional performance and recognize them as such. It can also show where improvements are needed. The data used is based on a set of mutually agreed performance measures. This will provide information for continuous improvement that can result in eliminating mistakes and will lead to ensuring that products are always meeting customer requirements. A supplier certification program is a way for organizations to identify suppliers who are the most committed to maintaining a partnership and who have the best capabilities. The results of a supplier certification are being able to reduce the supplier base, build long-term relationships, reduce time spent on incoming inspections, improving delivery, recognizing excellence, developing a commitment to continuous improvement and improving overall performance. Supplier recognition programs are another way to nurture a healthy supplier relationship. An award program is a good way to promote excellent supplier performance. This allows the award winner to serve as a role model for the other suppliers. The other suppliers will want to do better and also be recognized. Supplier relationship management involves streamlining the processes and communication between the buyer and seller using software applications to manage the processes more efficiently and effectively. Questions 1. What are the seven steps in the approach to supplier development? Answer: Identify critical goods and services, identify critical suppliers not meeting performance requirements, form a cross-functional supplier development team, meet with top management of suppliers, rank supplier development projects, define the details of the buyer-supplier agreement, and monitor project status and modify strategies. (Pages 89-90) 2. What are the two types of SRM? Answer: Transactional and analytic. (Page 94) 3. What are the three major cost categories? Answer: Pre-transaction, transaction and post-transaction. (Page 81) 4. Why is a supplier evaluation and certification process important? Answer: So organizations can identify their best and most reliable suppliers. (Page 82) 5. What are the benefits of investing in an environmental management system based on ISO4000 standards? Answer: Reduced energy and other resource consumption, decreased environmental liability and risk, reduced waste and pollution and improved community goodwill. (Page 89)

Saturday, November 9, 2019

How to make effective resume? Essay

RESUME: – Your resume is one of the most important tools you have when looking for a job. This page will help you choose the right type of rà ©sumà © for your situation. It will also provide you with tips to help you tailor your rà ©sumà © to the job you’re applying for, and to make sure it stands out in a crowd for all the right reasons. A resume is a short, point-form document that you give to employers to tell them about your work experience, education, and skills. Before you write your rà ©sumà ©, you may want to complete a skills inventory to know what skills you have to offer an employer. WHY DO YOU NEED A RESUME? The job market has changed drastically from just a few years ago. While a resume was once only needed by upper management and executives, today almost everyone needs a rà ©sumà © to job hunt effectively. The resume has only one purpose . . . to get interviews. A good resume cannot get you a job, but a bad resume or no resume will prevent you from even getting the opportunity to interview. A rà ©sumà © is a marketing tool, plain and simple. Your rà ©sumà © speaks for you when you are not there to talk yourself. Many companies want you to send your resume in response to an advertisement on the internet or in the newspaper. In order to remain anonymous and avoid a flurry of phone calls, they only list their fax number or an e-mail address. If you do not have a resume you will not be able to respond to these types of advertisements. Many people think of a rà ©sumà © as a history or summary of their career. This is not quite correct. What makes a well-written resume so effective is that it provides potential employers with relevant information about why they should consider hiring you. An effective resume will show the employer all the benefits they will receive from hiring you. An effective rà ©sumà © is an investment, whether in the time it takes you to prepare it yourself or if you decide to hire a professional to help you. However, a well-written resume is an investment in your future. Think about the salary you are costing yourself from missed opportunities and failing to convince employers to call you for an interview. A good rà ©sumà © will get you more calls, more interviews and therefore a job much more quickly. A great rà ©sumà © can also convince an employer you are worth more salary! Here are some key components that make an effective resume:- * YOUR RESUME MUST SELL AN EMPLOYER YOUR BENEFITS:- The process of looking for a job is a sales presentation. You have become a salesperson and the product you are selling is YOU! Any good salesperson will tell you that you have to sell a customer on the benefits they will receive from the product. Your customer, the prospective employer, wants to know how you will return the investment they will make in you as an employee. In other words, don’t just tell them you are organized; tell them you have the ability to bring order to any chaotic situation that will increase the efficiency of the office. Don’t just tell them you are dependable, let them know that you have a spotless record of attendance and you are never late. * YOUR RESUME MUST BE ERROR FREE: One type or one misspelled word could be the reason that hiring managers are not calling you. Proofread your rà ©sumà © forwards and backwards. Don’t rely on your computer’s spellchecker to catch your errors. Spellcheckers only find misspelled words; they don’t look for misused words. Consistency is very important when creating your document. Attention to detail in your rà ©sumà © communicates to the hiring manager that you pay attention to details in your work. * YOUR RESUME MUST BE PERSONALIZED:- Templates or cookie cutter resumes are a problem because they look just like everyone else resume. What you need is to stand out from the crowd. Remember, a resume’s job is to entice the hiring manager to call you for an interview. Anyone can write a resume for an administrative assistant. What will get your phone ringing for interviews is a resume that tells the hiring manager why you are a great administrative assistant. WHAT TO INCLUDE IN RESUME? CONTACT INFORMATION * HOBBIES OBJECTIVES * CERTIFICATES HIGHLIGHTS OF QUALIFICATION EDUCATION SKILLS EXPERIENCE EXTCURRICULUM ACTIVITIES AWARDS/HONOURS TYPES OF RESUMES:- *CHRONOLOGICAL RESUMES: – A chronological resume starts by listing your work history, with the most recent position listed first. Your jobs are listed in reverse chronological order with your current or most recent job, first. Employers typically prefer this type of resume because it’s easy to see what jobs you have held and when you have worked at them. This type of resume works well for job seekers with a strong, solid work history. * FUNCTIONAL RESUME: – A functional resume focuses on your skills and experience, rather than on your chronological work history. It is used most often by people who are changing careers or who have gaps in their employment history. * COMBINATION RESUME: – A combination resume lists your skills and experience first. Your employment history is listed next. With this type of resume you can highlight the skills you have that are relevant to the job you are applying for, and also provide the chronological work history that employers prefer. RESUME FORMAT Your Contact Information First Last Name Street Address City, State, Zip Phone (Cell/Home) Email Address Objective (optional) What do you want to do? If you include this section it should be a sentence or two about your employment goals. A customized objective that describes why you are the perfect candidate for the job can help your resume stand out from the competition. Career Summary / Highlights (optional) A customized section of your resume that lists key achievements, skills, traits, and experience relevant to the position for which you are applying can serve dual purposes. It highlights your relevant experience and lets the prospective employer know that you have taken the time to create a resume that shows how you are qualified for the job. Experience This section of your resume includes your work history. List the companies you worked for, dates of employment, the positions you held and a bulleted list of responsibilities and achievements. Company #1 City, State Dates Worked Job Title Responsibilities / Achievements Responsibilities / Achievements Company #2 City, State Dates Worked Job Title Responsibilities / Achievements Responsibilities / Achievements Education In the education section of your resume, list the schools you attended, the degrees you attained, and any special awards and honors you earned. College, Degree Awards, Honors Skills Include skills related to the position / career field that you are applying for i.e. computer skills, language skills. References available upon request There is no need to include references on your resume or even to mention that references are available. Rather, have a separate list of references to give to employers upon request. Customize Your Resume In all cases, be sure to personalize and customize your resume, so it reflects your skills and abilities and connects them with the jobs you are applying for. Review Resume Samples Review sample resumes so you can incorporate your resume template information into an appropriate format.

Thursday, November 7, 2019

Free Essays on Baglady-Best Friend

â€Å"Bag Lady Best Friends† I approached the homeless woman with caution and fear, not knowing what I would say to her. â€Å"Was this my former friend?† I asked myself. â€Å" Leisha?† I called out to the homeless woman with her back turned. Immediately her head turned around, and she quizzically replied â€Å"Yes?† At that moment my mind became clouded with emotions, I was shaking. I didn’t realize what I would say; I tensed up, my stomach was in pain. I mean, me and Leisha weren’t the best of friends all the time, but it was weird, no fucked up even to seem someone I knew so personally in this shape. While I stood there pondering all this information that flew in and out of my head, my friend turned bag lady stared with her lifeless eyes emptily into nothing. I stuttered and replied to her, â€Å"It me, you’re old friend Susan, Remember?† She shrugged me off and mumbled something inaudible under her breath. I could tell it was her, I could feel her presence. And although I haven’t seen her in years I could tell that under her terrible skin, and ragged clothes, and that utter displeasing stench lie my friend Leisha. I called out to her pleading desperately to make conversation, I wanted to help her, give her money, she could stay with me if she wanted to and I’m sure if her parents found out that their daughter was living in destitute on the cold streets on this city that they would easily nurture her back onto her feet. I tapped her on the shoulder, and wanted to yell in all my frustration, but I kept it inside. Instead I gently asked her again â€Å"Do you remember me Leisha, it’s Susan?† She didn’t respond. â€Å" I can help you Leisha, how did you let yourself get this way?† I asked. She asked me for some change. I reached in my pocket and generously gave my friend twenty dollars, she gladly accepted it. â€Å"Susan† She put my hand in hers and clenched. â€Å"Oh thank God â€Å"I thought. The connectio... Free Essays on Baglady-Best Friend Free Essays on Baglady-Best Friend â€Å"Bag Lady Best Friends† I approached the homeless woman with caution and fear, not knowing what I would say to her. â€Å"Was this my former friend?† I asked myself. â€Å" Leisha?† I called out to the homeless woman with her back turned. Immediately her head turned around, and she quizzically replied â€Å"Yes?† At that moment my mind became clouded with emotions, I was shaking. I didn’t realize what I would say; I tensed up, my stomach was in pain. I mean, me and Leisha weren’t the best of friends all the time, but it was weird, no fucked up even to seem someone I knew so personally in this shape. While I stood there pondering all this information that flew in and out of my head, my friend turned bag lady stared with her lifeless eyes emptily into nothing. I stuttered and replied to her, â€Å"It me, you’re old friend Susan, Remember?† She shrugged me off and mumbled something inaudible under her breath. I could tell it was her, I could feel her presence. And although I haven’t seen her in years I could tell that under her terrible skin, and ragged clothes, and that utter displeasing stench lie my friend Leisha. I called out to her pleading desperately to make conversation, I wanted to help her, give her money, she could stay with me if she wanted to and I’m sure if her parents found out that their daughter was living in destitute on the cold streets on this city that they would easily nurture her back onto her feet. I tapped her on the shoulder, and wanted to yell in all my frustration, but I kept it inside. Instead I gently asked her again â€Å"Do you remember me Leisha, it’s Susan?† She didn’t respond. â€Å" I can help you Leisha, how did you let yourself get this way?† I asked. She asked me for some change. I reached in my pocket and generously gave my friend twenty dollars, she gladly accepted it. â€Å"Susan† She put my hand in hers and clenched. â€Å"Oh thank God â€Å"I thought. The connectio...

Tuesday, November 5, 2019

Aging Population in Hk

In the past, many people dead in childhood due to sickness and improper medical treatment, which enzymes and bacteria can easily kill them. However, with the development of medical technology, such as introduction of new treatments like antibacterial, people can combat many diseases and have a longer life, and the death rate can be lowered. Hence, as Hong Kong is a stable place, it can make people in Hong Kong live longer. Hong Kong is a stable place without the threat of civil wars and lack of essential resources like water and food, compare with some undeveloped countries. In addition, the Hong Kong government also maintain stability by making policies such as food hygiene policy. With maintaining stability, people can live longer then. The above conditions lead to the increasing longevity of Hong Kong people, which caused the aging population in Hong Kong. Declining birth rate In the past 50 years, there was a baby boom occurred in Hong Kong. People at that time did not concern about the cost of bring the child up and the problem of population explosion, which lead to the high birth rate at that time. After reaching 1980s, the birth rate started to be declined. This is mainly due to higher education rate in HK, when there is a higher educates rate, less female would unwilling to born more children. Hence, fearing from financial burden, as it bringing a child up requires a high cost, families are unwilling to give birth to child. Moreover, people are more likely to settle down at a later age, form their families when they become old, this also lead to a low birth rate. In fact, the low death rate could bring few negative effects. However, when there is a declining birth rate, the young age group cannot support the size of old age group born in the baby boom. This will lead to a serious problem. In short, a declining birth rate and a low death rate caused the aging population. Situation in Hong Kong In Hong Kong, the population sizes of youngsters are keeping decreasing with a decrease of 17. 9% in 33 years. In contrast, the number of old people are keeping increasing, it is estimated in 2033, the old age group will become one-forth of the whole population. Hence, there is a decreasing trend in birth rate in 40 years with a drop of 1500 babies per year. Nevertheless, the trend grow again since 2005 due to migration from Mainlanders, they could only be able to work until 2030,which may hard to combat the problem. To conclude, the problem of aging population is serious. Impact of aging population In medical aspect, aging population may increase medical expenditure of government because elderly people may have the high risk of chronic diseases. Due to increases of medical services, the demand of doctor and nurses would also be increased. However, the government may not have enough money to provide better medical services as a lower tax income. This may lead to poor quality of medical services. From the point of view of the government, aging population reduces the government’s income as providing more welfare and medical care for elderly. It would also affect the GDP of HK due to more elderly people and less working population, which reduce Hong Kong’s economic development. HK competitiveness in the world may be seriously affected. In social aspect, aging population may increase the pressure of working force, as they need to pay more tax to government for providing better medical services and welfare, even though the demand of productivity at will be high and high salaries will be paid in the future. On the other hand, it may also enhance the problem of poverty as they may unable to work after retired. Suggestions of aging population From the above passage, we can see that aging population will cause a high expenditure and welfare on the government. The aims of the solutions below are to solve these problems. To start with, the government can solve the problem by Enabling older individuals to keep economically active. For example, the government can employed these old age people part-time works to enhance productivity. It can also encourage them to spend more money to enhance the economy by encourage them to travel in Hong Kong, such as the $2 Public Transport Concessions for the elderly. For those retired who are poor and disable to work, the government should put more resources to help them maintain a living. For example, increase the amount of welfare on the poor, or provide resources to some fund, which helps the old age groups, such as the Community Collusion Fund. On the other hand, the government should also cut some welfare, for example, the introduction of the Mandatory Provident Fund (MPF) can let the old people save money itself for entire when they are working; the issue of health care voucher can reduce the burden of the government-owned health system. These measures can help the government to reduce the welfare.

Saturday, November 2, 2019

Rhetoric & Stereotypes Essay Example | Topics and Well Written Essays - 500 words - 1

Rhetoric & Stereotypes - Essay Example ho are in the tattooed group are considered to be freaks, drug, addicts, criminals, weirdoes, tough and are always around bad people (Macrae, Stangor, Miles, 1996). These stereotypes are all negatives. The senior citizen group is taken to be made of people who are unwilling to accept new things, stuck in the past, silent and low movers who are hard at hearing. These stereotypes are both positive and negatives. Politicians use what looks like rational language that may in fact be false in their speeches so as to satisfy their own desires and interests. Another language common with the politicians is personal attack ad hominem (Bodenhausen and Macrae, 1994). The language is mostly used to shield the politician from the other groups of politicians. Usually this is done in a show of dislike for the other individual. A common language among the tattooed people is subjectivism (Macrae, Stangor, Miles, 1996). This is based on the assumption that whatever is true to an individual may not be true to the other. The language is used to justify their acts of misbehavior because most tattooed people are associated with negative activities. The feminist get a lot of attacks as many people do not want to accept their way of life hence they are never approved and are considered to be weak. Scare tactics are used to undermine their efforts to justify their way of living within the society (Ninvalle, 2004). The stereotypes are meant to undermine or intimidate someone into not doing some things. For example, a feminist can be intimidated due to the fact she is a woman and women are considered weak within the society. Senior citizens are the most neglected and stereotyped people within the society and the language commonly used is genetic fallacy according to Bodenhausen and Macrae (1994). This involves rejecting a claim based on origin or history. These stereotypes are usually half truths and they are based on assumptions that have little or no evidence. In conclusion, the

Thursday, October 31, 2019

Buffers and Buffer Capacity Essay Example | Topics and Well Written Essays - 1000 words

Buffers and Buffer Capacity - Essay Example Afar its buffering range, a buffer does not act to stabilize the pH of the solution (Phadungchewit, 13). Buffers are very essential to living organism. This is since most biochemical progressions occur only when the pH is within a narrow range. Excessive consumption or intake of H+ or OH- can constrain the system and action of several biomolecules, particularly proteins. Thus, buffers are generally used in living organisms to assist in the maintenance of a relatively stable pH. For instance in humans, buffers help to maintain the blood pH within a range of between 7.35 and 7.45. Buffer capacity is denoted ï  ¢ and as it increases, the ability to resist change in pH also increases (Yuwaree, 15). This is represented by the equation: ï  ¢ Is the buffer capacity (numerical indicator showing how the buffered solution resists the change in pH. If solution is well buffered ï  ¢ gets bigger, if poorly buffered it gets small. The (i) and (i+1) are the two successive data points in a pH titration. And finally V is the base volume. First, 100 mls of NaOH solution is prepared from o.1M of the available NaOH titrant. Secondly, HCl solution is prepared by the dilution of a 90.0 mM HCl solution present from the TA. Finally, the concentration of 3.0mM of citric acid solution is prepared by weighing out within a range of ï‚ ± 1% and dissolving in it an appropriate quantity of citric acid (Pohland, Frederick, 23). Calibrate a pH meter by use of pH7 along with 4 buffers. Put the solution of HCl and measure the value of pH during the stirring process. By use of a burette, add contents of 0.5ml increments of the NaOH titrant then make recordings of the pH and the volume of the base added. For the stable recording, we waited for few seconds for the pH meter in order to acquire most accurate results. We began by adding two drops of NaOH into Each of the acid beaker after observing abnormal increase in pH value. We stopped when the pH meter read (9.19). We repeated

Tuesday, October 29, 2019

Deluxe Financial Services Assignment Example | Topics and Well Written Essays - 500 words

Deluxe Financial Services - Assignment Example The firm’s slogan, printing paper checks faster and better, and more economically than anyone else, has attracted many customers to the firm. The firm’s policies regarding its proceedings and its customers have made it reach the level where it is (Clancy & Hartley, 2011). Deluxe decided to change its policy from a check printing firm to a sophisticated check retailing company. The firm maintained this approach to transformation, opting to try out new services and new customers (Clancy & Hartley, 2011). The firm presented a breakthrough known as DeluxeSelect. The invention was powered by richly detailed consumer segments profiles, which comprised of information regarding what type of check a consumer wanted. The DeluxeSelect invention also catered for the way consumers needed their checks, how they wanted the firm to communicate with them and the price they were willing to pay (Clancy & Hartley, 2011). This was the ultimate invention in the check business, and this attracted a lot of customers to the firm. The firm, therefore, went ahead to erect policies, which would maintain their customers. Deluxe rule is to put employees and customers first. Everything else, according to the firm, comes second. As expected, this has attracted many clients to the fi rm and maintained them. Deluxe is capable of handling many customers with fewer hurdles, and this has enabled the firm to grow (Clancy & Hartley, 2011). The economy, today, is turning against the people who use it. Peoples’ income, today, cannot cater to everything they need, and this has made them cut some expenses from their budget (Lowry, 2012). However, as this happens, global firms such as Coca-Cola still seem to be making the large profits, which they used to make before the economic crises. In fact, it is like the firm is getting more funds at this crucial time. It is all a matter of how Coca-Cola advertises itself (Lang, 2012).

Sunday, October 27, 2019

Vibrational frequencies of water molecule

Vibrational frequencies of water molecule Question 1 Normal modes and vibrational frequencies of water molecule HF/3-21* optimised geometry of the water molecule H bond length 0.967 HOH bond angle 107.7 (ii) Energy of the HF/3-21G optimised water molecule = -75.58596 au Cycle Energy Max. Grad. Max. Dist. 1 75.58553 0.01246 0.00304 2 75.58589 0.00324 0.00025 3 75.58596 0.00001 0.00000 Frequency (cm-1) Relative Motion Stretch or Bend Type Symmetry (S or A) 1799.2 Bend A1 S 3812.2 Stretch A1 S 3945.8 r Stretch B1 A HOD Energy 75.58596 au Geometry Bond angle 107.7 Bond length 0.967 Vibrational frequencies 1578.7 H moves faster than D symmetric 2815.3 D moves quickly whereas H moves slightly asymmetric 3881.7 H moves quickly whereas D moves slightly asymmetric Normal modes and vibrational frequencies of the water dimmer (H2O)2 Hydrogen-Bond Acceptor Hydrogen bond Hydrogen Bond Donor Hydrogen bond length (HO) = 1.808 Hydrogen bond angle (O-HO) = 174.9 Energy of the F/3.12G optimised water dimer = -151.18902 au (a) Potential energy calculation: ΔE = E(dimer) 2xE(H2O) = (-396 871.2KJ/mol) 2x(-198 413.2KJ/mol) = (-396 871.2) (-396 826.3) = 44.9 KJmol-1 (b)As seen from the surface diagram for H2O, the oxygen has negative charge (ÃŽ ´-) whereas the hydrogens are positively charged (ÃŽ ´+). In the water dimer molecule, the hydrogen atoms (on the H-bond donor oxygen) are ÃŽ ´+/blue region. The oxygen atom that is bonded to the hydrogen that is the H-bond acceptor has ÃŽ ´- charge/red region. Between in the H-bond, the positive(H) and negative(O) charges combine/green region. The hydrogen bond is formed between one of the H atoms and one O, instead between the two oxygens, because the two oxygen atoms are negatively charged, and have ÃŽ ´-, and therefore repulsive interactions are formed between them. So, one H reacts with the O, which donates one of its lone pairs to form the H-bond. In the structure of the molecule, the HO bond is almost linear, very close to 180 but it is distorted so it is about 175. Also, the distortion causes the bond HO to become longer. (c) For the water molecule: H bond length = 0.967 For the water dimer: H bond length of H-bond donor = 0.965 H bond length of H-bond acceptor = 0.966, 0.974 (H of H-bond) The H bond length of the hydrogen of the H-bond is bigger than the other O-H bonds in the molecule. This is because this H is bonded to the oxygen through the H-bond, and it is pulled towards the oxygen, causing its bond with the other oxygen to become a bit longer. Question 2 The water dimer consists of two fragments, the H-bond acceptor (top OH2 group) and the H-bond donor (bottom OH2 group). When a vibration causes both fragments and H-bond to move, then it is considered to be the inter-monomer because it is a vibration between the two molecules. If only one of the fragments vibrates, then the vibration is only in one of the molecules (it is internal) and it is considered to be an intra-monomer. The vibrational frequencies of the water dimer are the following: Frequency = 81 cm-1 Type = A Bending Mode Top part of the molecule moving slightly up and down, while the two bottom hydrogens move up and down as well Inter-monomer: The vibration affects both molecules connected through the hydrogen bond. Frequency = 133 Type = A Bending mode Top part and bottom part moving right and left. Inter monomer Frequency = 172 Type = A Bending mode Middle hydrogen moving right and left and two bottom H atoms moving up and down symmetrically (when one is up, other is down) Inter Monomer Frequency = 242 Type = A Stretching Mode Inter monomer Frequency = 425 Type = A Bending Mode The H-bond acceptor fragment moves to the front and then back, and the H-bond donor fragment moves up and down as well. Inter-monomer Frequency = 826 Type = A Bending mode The H of the H-bond (middle H) is moving to the right and left, causing the rest of the molecule to move in that way as well Inter-monomer Frequency = 1782 Type = A Bending Mode The hydrogen atoms on the H-bond donor fragment move up and down to the sides going further away and then coming closer. Intra-monomer Frequency = 1854 Type = A Bending Mode The hydrogen atoms on the H-bond acceptor fragment separate and go further away and then come closer together again. Intra-monomer Frequency = 3724 Type = A Stretching mode The hydrogen forming the H-bond moves closer to the oxygen of the H-bond and then further from it, causing the O-H bond to come smaller and the HO bond to become bigger, and the opposite. Intra-monomer Frequency = 3849 Type = A Stretching mode The hydrogen atoms move symmetrically so that their bonds with the O of the H-bond donor are becoming bigger (stretch out) and then smaller. Intra-monomer Frequency = 3907 Type = A Stretching mode The O-H bond of the H not involved in the H-bond acceptor fragment is stretching out, causing the bond to become longer, while the bond of the oxygen with the other H, which is involved in the H-bond, becomes shorter. Intra-monomer Frequency = 3982 Type = A Stretching mode It is an unsymmetrical movement, where one O-H bond in the H-bond donor fragment becomes shorter and the other longer. Intra-monomer Question 3 Isotopic substitution in the water dimer Free Energy (H-TS) = 37.8 ΔÎâ€" Total = 127.5 Free Energy (H-TS) = 39.7 ΔÎâ€" Total = 126.5 ΔG = G(B) G(A) = 39.7KJmol-1 37.8KJmol-1 = 1.9 KJ/mol K = e(-ΔG/RT) = exp(-1.910-3Jmol-1/8.314JK-1mol-1x298K) = 1.00000077 Deuterium prefers the position shown in B (connected to the oxygen of the H-bond acceptor fragment, but doesnt take part directly in the H-bond) because the molecule has higher free energy for this arrangement. Question 4 Interconversion of water dimer structures Frequency = i302 Type = B1 Frequency = 105 Type = B2 Frequency = 208 Type = A1 Frequency = 225 Type = B1 Frequency = 256 Type = A2 Frequency = 591 Type = B2 Frequency = 1785 Type = A1 Frequency = 1831 Type = A1 Frequency = 3829 Type = A1 Frequency = 3862 Type = A1 Frequency = 3952 Type = B1 Frequency = 3961 Type = B2 Acyclic water dimer Cyclic water dimer The acyclic water molecule energy is 3.96910-5 KJmol-1 whereas the energy of the cyclic one is -. The cyclic molecule is less stable than the acyclic one because its ability to move around is effectively reduced compared to the acyclic one, due to the two bonds formed between the oxygen of one molecule and the two H of the other molecule. The imaginary frequency has the value of i306.9. One of the middle hydrogens moves up while the other moves down, in an unsymmetrical movement as shown in the pictures above. For the acyclic water dimer there are no imaginary frequencies and it corresponds to the valley. This shows that it is very stable and this structure is preferred. The cyclic molecule contains one vibrational frequency and this suggests that it is not as stable as the acyclic one. It corresponds to the hilltop of molecule-mountain. If a molecule has more than one vibrational frequency it corresponds to the mountain passes and it is a very unstable and unfavoured structure for the molecule to be at, which most probably does not exist. The cyclic structure is not very stable, and therefore it is not preferred over the acyclic one. Question 5 Syn-butane: No imaginary frequencies à   Valley à   stable structure, highly favoured Boat cyclohexane: ne imaginary frequency à   Hilltop à   fairly unstable, exists but not preferred All-syn cyclohexane: More than one imaginary frequencies à   Mountain Pass à   does not exist, very unstable

Friday, October 25, 2019

Essay --

It is difficult to know whether a negative reaction to the leader or other members in the group is because of a true feeling toward that person, or if it is because of transference of feelings for someone significant in the life of the person having the reaction. One of the most obvious signs that there is transference taking place is when a member has a really strong reaction to me, the leader, without having spent much time with each other. I think this is the most obvious because how could such strong feelings transpire in such a short period of time. Another sign is negative feelings over time. There may be a way that I behave or articulate myself that brings up feelings of someone in the member’s outside life. After all of the reading that we have done for this class though, I feel like the only way to really know if it is transference is to discuss what the individual is feeling and why they think they are having such a strong reaction. Transference between members is probably more obvious. The leader can look at the interactions between members more objectively. The signs are the same as transference toward the leader, but the members that seem to be in conflict may not understand what is potentially happening. Just like with transference toward the leader, discussion about feelings and personal reactions needs to take place. 2. There are a few steps that I can take to be more aware of if I am having some countertransference reactions to members. First, understanding my own issues with people in my life. If I am having issues with someone in my life, then a member exhibits behavior in the group that I associate with the individual in my personal life, I cannot provide the best help to them. Next, if I am having strong re... ...goals they will have for themselves when the group does end. Once they establish the goals they would like to achieve when the group ends, the leader can help guide them in ways to reach those goals. My job as a leader would be to help the members deal with their feelings about the group ending. As the reading makes clear some people may have anxiety about not having the support of the group, or maintaining the changes that they have made. I also will need to address any concerns about confidentiality once the group ends. The members need to know that the work they did is going to stay confidential, even though the group is ending. Helping members set goals and the ways they can achieve them when the group ends is also important. Giving any final feedback that can help the members after the final session will also aid in the member in reaching/setting their goals.